[1,1′-Bis(Diphenylphosphino) Ferrocene] Dichloropalladium(II) , 72287-26-4 , Pd(Dppf)Cl2
[1,1′-Bis(Diphenylphosphino) Ferrocene] Dichloropalladium(II) , 72287-26-4 , Pd(Dppf)Cl2
[1,1′-Bis(Diphenylphosphino) Ferrocene] Dichloropalladium(II) , 72287-26-4 , Pd(Dppf)Cl2
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[1,1′-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium(II)

Identification
Name
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Synonyms

dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) complex;

1,1'-Bis(diphenylphosphino)ferrocenedichloropalladium(II)

(dppf)2PdCl2;
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropall;
(II)dichloromethane adduct;
[1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex;

Pd(dppf)Cl2;


Molecular Structure
72287-26-4

Molecular Formula
C34H28Cl2FeP2Pd
Molecular Weight
731.71
CAS Registry Number
72287-26-4
Properties
Palladium content
>14.5%
purity

≥99%min
Property
air and moisture sensitive
Specification
Analytical pure
Application
Catalyst, Carbonylation, Cross-coupling reaction, Suzuki reaction
Melting point
275-280 ºC
Appearance
Orange red powder
Solubility

Soluble in dichloromethane.
Safety Data
Hazard Symbols
Xn
Risk Codes
R20/21/22
Safety Description
S36/37

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Uses:

[1,1'-Bis(diphenylphosphino)ferrocene]palladium dichloride (PdCl2(dppf)) as a catalyst is mainly used to catalyze the cross-coupling reaction. Similar to other Pd(II) and Ni(II) complexes, PdCl2(dppf) can effectively catalyze the cross-coupling reaction between halogenated olefins, halogenated aromatic hydrocarbons or trifluoromethanesulfonate aromatic hydrocarbons and Grignard reagents. Achieve the formation of carbon-carbon bonds.

Catalyst for carbonylation reaction, cross-coupling reaction, Suzuki reaction.C-C and C-N coupling reaction catalyst.


[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Preparation:

A preparation method of 1,1'-bis(diphenylphosphino)ferrocene palladium dichloride II (dppfPdCl2), including the following steps:

(A) Add palladium chloride to concentrated hydrochloric acid and heat to 40-80℃ to dissolve. The amount of hydrochloric acid is 0.2-1.0 times the mass of palladium chloride. Add ethanol to dilute Chemicalbook to release. The amount of ethanol is 10- of the mass of palladium chloride. 50 times;

(B) Add bisdiphenylphosphinoferrocene (dppf) of 3.0-5.0 times the mass of palladium chloride to the tetrahydrofuran solution, and heat to 40-80°C until it dissolves. The amount of tetrahydrofuran is 20% of the mass of palladium chloride. -30 times;

(C) Add the solution obtained in step (a) dropwise to the solution obtained in step (b), keep it at 45-80°C for 0.5-3h after dropping, then cool, filter, wash, and vacuum dry to obtain 1, 1'-Bis(diphenylphosphino)ferrocene palladium dichloride II red crystals.


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